کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1285896 | 973164 | 2008 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Study of fuel efficiency in a direct borohydride fuel cell Study of fuel efficiency in a direct borohydride fuel cell](/preview/png/1285896.png)
In this study, direct borohydride fuel cells (DBFCs) potentialities are evaluated. These emerging systems make it possible to reach maximum powers of about 200 mW cm−2 at room temperature and ambient air (natural convection) with high concentrated borohydride solutions. On the other hand, a part of borohydride hydrolyses during cell operating which leads to hydrogen formation and fuel loss: the practical capacity represents about only 18% of the theoretical one. In order to improve fuel efficiency, thiourea is tested as an inhibitor of the catalytic hydrolysis associated with BH4− electro-oxidation on Pt. The practical capacity is drastically improved: it represents about 64% of the theoretical one. Against, electrochemical performances (I–E curves) are affected by the presence of thiourea.Last, both playing with platinum anodic mass loading and the nature of catalyst, a good compromise has been found in terms of both specific capacity and power.
Journal: Journal of Power Sources - Volume 176, Issue 1, 21 January 2008, Pages 287–292