کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1286626 1497965 2014 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
4-(Trifluoromethyl)-benzonitrile: A novel electrolyte additive for lithium nickel manganese oxide cathode of high voltage lithium ion battery
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
4-(Trifluoromethyl)-benzonitrile: A novel electrolyte additive for lithium nickel manganese oxide cathode of high voltage lithium ion battery
چکیده انگلیسی


• 4-TB is used as a novel electrolyte additive for high voltage lithium ion battery.
• Cyclic stability of LiNi0.5Mn1.5O4 is improved significantly by using 4-TB.
• 4-TB is oxidized preferably to carbonate solvents forming a low-impedance protective film.
• The film suppresses subsequent decompositions of electrolyte and LiNi0.5Mn1.5O4.

In this work, 4-(Trifluoromethyl)-benzonitrile (4-TB) is used as a novel electrolyte additive for LiNi0.5Mn1.5O4 cathode of high voltage lithium ion battery. Charge–discharge tests show that the cyclic stability of LiNi0.5Mn1.5O4 is significantly improved by using 0.5 wt.% 4-TB. With using 4-TB, LiNi0.5Mn1.5O4 delivers an initial capacity of 133 mAh g−1 and maintains 121 mAh g−1 after 300 cycles with a capacity retention of 91%, compared to the 75% of that using base electrolyte (1 M LiPF6 in ethylene carbonate(EC)/dimethyl carbonate(DMC)). The results from linear sweep voltammetry, density functional theory calculations, electrochemical impedance spectroscopy, scanning electron microscope, energy dispersive spectroscopy, Fourier transform infrared, and inductively coupled plasma, indicate that 4-TB has lower oxidative stability than EC and DMC, and is preferentially oxidized on LiNi0.5Mn1.5O4 forming a low-impedance protective film, which prevents the subsequent oxidation decomposition of the electrolyte and suppresses the manganese dissolution from LiNi0.5Mn1.5O4.

Improved cyclic stability of LiNi0.5Mn1.5O4 by using 0.5 wt.% 4-TB.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 267, 1 December 2014, Pages 560–565
نویسندگان
, , , , , , ,