کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1287202 | 1498039 | 2006 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Organic compounds with heteroatoms as overcharge protection additives for lithium cells Organic compounds with heteroatoms as overcharge protection additives for lithium cells](/preview/png/1287202.png)
Various organic compounds with heteroatoms (N, O, F, Si, P, S) were tested as overcharge protection additives for 4-V class lithium cells. It was found that trimethyl-3,5-xylylsilane exhibited preferable oxidation potential (Eox) as overcharge protection additive, and charge–discharge cycling efficiency (Eff) of lithium anode in electrolyte with arylsilanes was as high as tolyladamantanes, reported previously by us. From room temperature to 60 °C, Eox of trimethyl-3,5-xylylsilane decreased only 0.07 V. Difference in Eox among regioisomers of tolyltrimethylsilanes is smaller than that among tolyladamantanes. 1H NMR and UV spectra suggest the steric repulsion between tolyl group and trimethylsilyl group in o-tolyltrimethylsilane is smaller than that of the related substituents of o-tolyladamantane.
Journal: Journal of Power Sources - Volume 160, Issue 2, 6 October 2006, Pages 1375–1380