کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1287874 | 1497997 | 2013 | 8 صفحه PDF | دانلود رایگان |
A monolithic quasi-solid-state dye-sensitized solar cell assembled with an iodine-free polymer gel electrolyte (IFGE) and a printable mesoscopic carbon counter electrode was developed. The IFGE was prepared by employing an ionic liquid (1,2-dimethyl-3-propylimidazolium iodide, DMPII) as the charge transfer intermediate and a polymer composite as the gelator without the addition of iodine, exhibiting high conductivity and non-absorption characters. The dependences of ionic conductivity and photovoltaic performance on DMPII concentration in the IFGE were investigated. An overall power conversion efficiency (PCE) of 4.94% could be obtained for the IFGE with an ionic conductivity of 21.18 mS cm−2 under 100 mW cm−2 AM 1.5 illumination. The effects of additives lithium iodide (LiI) and N-methylbenzimidazole (NMBI) on the photovoltaic performance of the devices were also investigated. An optimal efficiency of up to 6.97% was obtained and the results were substantiated by incident photon-to-current conversion efficiency (IPCE) spectrum, electrochemical impedance spectroscopy (EIS) and intensity modulated photovoltage spectroscopy (IMVS) measurements.
► Monolithic dye-sensitized solar cell using iodine-free electrolyte is developed.
► The electrolyte presents high conductivity and non-absorption characters.
► A high efficiency of up to 6.97% has been obtained.
► The effect of additives on the device has been thoroughly investigated.
Journal: Journal of Power Sources - Volume 235, 1 August 2013, Pages 243–250