کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1287966 1497998 2013 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hierarchically porous carbon nanofibers containing numerous heteroatoms for supercapacitors
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Hierarchically porous carbon nanofibers containing numerous heteroatoms for supercapacitors
چکیده انگلیسی

In this study, hierarchically porous carbon nanofibers (HPCNFs) containing numerous electroactive heteroatoms are prepared by controlling carbonization and chemical activation. The HPCNFs have a large surface area of 2862.1 m2 g−1, hierarchical porous structure, and 20.6 at% electroactive oxygen atoms. These HPCNFs exhibit excellent electrochemical performance, and their thermal treatment with melamine results in nitrogen-doped HPCNFs (N-HPCNFs) with 9.1 at% nitrogen and improved electrical property (1.8 × 102 Ω □−1). The electrochemical performance of N-HPCNFs is better than that of HPCNFs, displaying specific energy of 113 Wh kg−1, specific power of 105 kW kg−1, and stable cycle life of over 5000 cycles.


► Hierarchically porous carbon nanofibers containing heteroatoms were prepared.
► Hierarchical structure was induced by controlling carbonization and activation of electrospun nanofibers.
► High specific energy (113 Wh kg−1) and power (105 kW kg−1) was achieved.
► A stable cycle life over 5000 cycles was also achieved.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 234, 15 July 2013, Pages 285–291
نویسندگان
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