کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1288080 | 1645393 | 2013 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Preparation and characterization of size-uniform Li[Li0.131Ni0.304Mn0.565]O2 particles as cathode materials for high energy lithium ion battery Preparation and characterization of size-uniform Li[Li0.131Ni0.304Mn0.565]O2 particles as cathode materials for high energy lithium ion battery](/preview/png/1288080.png)
Lithium-rich layered oxide, Li[Li0.131Ni0.304Mn0.565]O2 with uniform particle size, is prepared through co-precipitation of metal hydroxide with synergistic dispersion of polyvinylpyrrolidone and ethylene glycol and subsequent solid reaction with lithium hydroxide. The crystal structure and morphology of the prepared sample is characterized with X-ray diffraction and scanning electron microscope. It is found that the prepared sample is a solid solution of Li2MnO3 and LiNi0.5Mn0.5O2, with uniform particle size of about 230 nm. Charge/discharge tests indicate that the prepared sample exhibits improved elevated-temperature discharge capacity and cycling stability. In the region of 3.0–4.8 V, the prepared sample delivers initially a 0.1 C (1 C = 263 mAh g−1) capacity of 256 mAh g−1 at 50 °C and 205 mAh g−1 at 25 °C, and the 0.1 C capacity at 25 °C retains 178 mAh g−1 after 60 cycles. The capacity decay mechanism is understood in detail through dQ/dV analyses.
► Li[Li0.131Ni0.304Mn0.565]O2 was prepared by PVP and EG-assisted co-precipitation.
► Prepared sample delivers a high capacity with good cycle stability and rate performance.
► Capacity decay is related to solubility and structural rearrangement of metal ions.
Journal: Journal of Power Sources - Volume 230, 15 May 2013, Pages 89–95