کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1288292 | 1498005 | 2013 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: High-performance graphite negative electrode in a bis(fluorosulfonyl)imide-based ionic liquid High-performance graphite negative electrode in a bis(fluorosulfonyl)imide-based ionic liquid](/preview/png/1288292.png)
We evaluated the charge–discharge behavior of a graphite electrode in a 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)imide (EMImFSI) ionic liquid. According to the charge–discharge tests, the graphite negative electrode exhibited a high rate of performance in LiTFSI/EMImFSI (TFSI− = bis(trifluoromethylsulfonyl)imide) in the voltage range of 0.005–1.5 V (vs. Li/Li+), and the performance was comparable to that in a conventional organic solution-based electrolyte, LiPF6/EC+DMC. Moreover, the addition of LiBOB (=lithium bis(oxalato)borate) improved the rate capability and low-temperature operation of the graphite negative electrode, most likely owing to the low-resistivity solid electrolyte interface (SEI) derived from LiBOB. These results suggest that EMImFSI is a suitable electrolyte for lithium-ion batteries utilizing graphite negative electrodes and that optimization of the electrolyte composition with an additive can improve battery performance.
Figure optionsDownload as PowerPoint slideHighlights
► High-rate capability of a graphite anode can be achieved through the use of an FSI-based ionic liquid electrolyte.
► Highly stable cycling was obtained by the use of the FSI-based ionic liquid electrolyte, even at 60 °C.
► High-performance graphite anode at low-temperature was achieved by using the FSI-based ionic liquid with a LiBOB additive.
Journal: Journal of Power Sources - Volume 227, 1 April 2013, Pages 60–64