کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1289019 | 973280 | 2010 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Application of bis(fluorosulfonyl)imide-based ionic liquid electrolyte to silicon–nickel–carbon composite anode for lithium-ion batteries Application of bis(fluorosulfonyl)imide-based ionic liquid electrolyte to silicon–nickel–carbon composite anode for lithium-ion batteries](/preview/png/1289019.png)
An ionic liquid electrolyte containing bis(fluorosulfonyl)imide (FSI) anion without any solvent is applied to a silicon–nickel–carbon (Si–Ni–carbon) composite anode for rechargeable lithium (Li)-ion batteries. The FSI-based ionic liquid electrolyte successfully provides a stable, reversible capacity for the Si–Ni–carbon anode, which is comparable to the performance observed in a typical commercialized solvent-based electrolyte, while a common ionic liquid electrolyte containing bis(trifluoromethanesulfonyl)imide (TFSI) anion without FSI presents no reversible capacity to the anode at all. Ac impedance analysis reveals that the FSI-based electrolyte provides very low interfacial and charge-transfer resistances at the Si-based composite anode, even when compared to the corresponding resistances observed in a typical solvent-based electrolyte. Galvanostatic cycling of the Si-based composite anode in the FSI-based electrolyte with a charge limitation of 800 mAh g−1 is stable and provides a discharge capacity of 790 mAh g−1 at the 50th cycle, corresponding to a cycle efficiency of 98.8%.
Journal: Journal of Power Sources - Volume 195, Issue 18, 15 September 2010, Pages 6153–6156