Transient behavior analysis of a new designed passive direct methanol fuel cell fed with highly concentrated methanol

A new structure of passive direct methanol fuel cell (DMFC) with two methanol reservoirs separated by a porous medium layer is designed and a corresponding mathematical model is presented. The new designed passive DMFC can be directly fed with highly concentrated methanol solution or neat methanol. The porosity (ɛpr) of the porous medium layer is optimized using the proposed model. Some operation parameters are also optimized by both the numerical calculation and experimental measurement. The new designed DMFC can be continuously operated for about 4.5 times longer than a conventional passive DMFC with the optimum parameters. The methanol crossover during the same discharging is only about 50% higher.

Research highlights▶ A passive DMFC is manufactured for high concentration or neat methanol feeding. ▶ This design wouldn’t increase the CO2 releasing resistance. ▶ The new DMFC can continuously operate about 4.5 times longer than a conventional DMFC.