کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1290070 | 973319 | 2010 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: The effect of platinum in a Nafion membrane on the durability of the membrane under fuel cell conditions The effect of platinum in a Nafion membrane on the durability of the membrane under fuel cell conditions](/preview/png/1290070.png)
The effect of platinum on free radical generation and membrane degradation in proton exchange membrane (PEM) fuel cells is investigated using three typical cell configurations. Examinations of the fluoride emission rates (FERs) under different testing conditions indicate that platinum deposited in the membrane plays an important role as a catalytic center for the formation of H2O2 and HO free radicals, leading to PEM degradation. The chemical durability of the membranes is tested in accelerated Fenton tests. It confirms the formation of free radicals in the presence of platinum in the decomposition of H2O2 by colorimetric method with dimethyl sulfoxide (DMSO) as the trapping agent. In addition, structural and morphological changes of the membranes are characterized using FT-IR spectroscopy and scanning electron microscopy (SEM).
Journal: Journal of Power Sources - Volume 195, Issue 15, 1 August 2010, Pages 4606–4612