کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1290274 | 973322 | 2008 | 6 صفحه PDF | دانلود رایگان |

Rotating ring-disc electrode (RRDE) voltammetry is applied for the in situ determination of hydroxy borohydride (BH3(OH)−) formation during borohydride (BH4−) electro-oxidation on a gold (Au) electrode in 6.0 M NaOH solution. The BH3(OH)− is detected at the ring electrode due to its further oxidation to BH2(OH)2− by maintaining its potential in the range of −0.800 to −0.600 V vs. normal hydrogen electrode (NHE) while oxidizing BH4− on the disc electrode. The study reveals that the generation of BH3(OH)− increases if the anodic polarization of the disc electrode is increased. The RRDE ring-shielding experiments show that the electro-oxidation of BH4− occurs over a wide potential range of −0.500 to 0.400 V on the Au electrode under hydrodynamic conditions. Chronoamperometry is also used to study the BH3(OH)− oxidation in the potential range of −0.800 to −0.600 V with 0.33 M NaBH4 in three different buffer solutions of pH 10.2, 11.0 and 11.70, respectively. The chronoamperometric studies indicate that the formation and stability of BH3(OH)− depends on the pH value.
Journal: Journal of Power Sources - Volume 182, Issue 1, 15 July 2008, Pages 106–111