کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1290437 | 973325 | 2008 | 5 صفحه PDF | دانلود رایگان |

Li(Ni0.8Co0.1Mn0.1)O2 cathode materials were synthesized by solid-state reaction route. Single-phase layer structure with hexagonal unit cell having R3¯m symmetry was obtained and the average particle size was around 6 μm. Electrochemical studies showed single redox reaction and a maximum charging capacity of ∼140 mAh g−1 was obtained. Ex situ structural studies by X-ray diffraction and Raman scattering at various stages of charging and discharging showed that the host layered structure is maintained throughout the electrochemical lithiation–delithiation processes in the 3–4.5 V range with systematic change in the lattice parameters. First discharge capacity was 132 mAh g−1 and the capacity retention was ∼86% after 20 charge–discharge cycles.
Journal: Journal of Power Sources - Volume 183, Issue 2, 1 September 2008, Pages 761–765