کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1291049 | 973347 | 2006 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
An NMR spectroscopic study of water and methanol transport properties in DMFC composite membranes: Influence on the electrochemical behaviour
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
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چکیده انگلیسی
Water and methanol transport properties through bare recast Nafion and composite Nafion membranes containing ceramic fillers characterised by different acid-base behaviour were investigated by nuclear magnetic resonance (NMR) spectroscopy. The water self-diffusion coefficients were determined for the different membranes in the temperature range from 25 to 150 °C; the methanol self-diffusion coefficients were recorded for the most performing composite membrane (Nafion-SiO2) and compared to the bare Nafion membrane. Water and methanol transport characteristics of these membranes were correlated to the electrochemical behaviour in direct methanol fuel cells. NMR and electrochemical polarization data indicate that both electrical properties and transport mechanism are influenced by the surface properties of the inorganic fillers; there is a clear evidence that acidic fillers such as silica promote the proton transport in the membrane with respect to basic alumina.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 163, Issue 1, 7 December 2006, Pages 52-55
Journal: Journal of Power Sources - Volume 163, Issue 1, 7 December 2006, Pages 52-55
نویسندگان
V. Baglio, A.S. Aricò, V. Antonucci, I. Nicotera, C. Oliviero, L. Coppola, P.L. Antonucci,