کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1292045 | 973380 | 2006 | 16 صفحه PDF | دانلود رایگان |
Considerable ongoing research exists in the area of fuel cells for power and distributed power generation. Of the various types of fuel cells, phosphoric acid fuel cell (PAFC) is a mature technology and is under limited production in various parts of the world. Electrochemical impedance spectroscopy (EIS) is a powerful tool which can be used for characterization of PAFC cathodes. In EIS, the electrode response is analyzed against an equivalent electrical circuit for diagnostics. A shortcoming of this approach is that multiple circuits can match the same response and correlating the physical electrode parameters with the circuit components may become quite difficult. To avoid this, a mathematical model of the PAFC cathode that is easy to solve is developed. The relative value and position of the maximum phase angle with respect to frequency is proposed as a diagnostic marker. A diagnostics table based on this marker is developed using the simulation of the mathematical model and the results are experimentally verified.
Journal: Journal of Power Sources - Volume 161, Issue 2, 27 October 2006, Pages 971–986