کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1292590 | 973390 | 2006 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: LiFePO4/carbon cathode materials prepared by ultrasonic spray pyrolysis LiFePO4/carbon cathode materials prepared by ultrasonic spray pyrolysis](/preview/png/1292590.png)
Small crystallites LiFePO4 powder with conducting carbon coating can be synthesized by ultrasonic spray pyrolysis. Cheaper trivalent iron ion is used as the precursor. The pure olivine phase can be prepared with the duplex process of spray pyrolysis (synthesized at 450, 550 or 650 °C) and subsequent heat-treatment (at 650 °C for 4 h). The results indicate that the pyrolysis temperature of 450 °C is appropriate for best results. The carbon coating on the LiFePO4 surface is critical to the electrochemical performance of LiFePO4 cathode materials of the lithium secondary battery, since the carbon coating does not only increase the electronic conductivity via carbon on the surface of particles, but also enhance the ion mobility of lithium ion due to prohibiting the grain growth during post-heat-treatment. The carbon of 15 wt.% evenly distributed on the final LiFePO4 powders can get the highest initial discharge capacity of 150 mA h g−1 at C/10 and 50 °C.
Journal: Journal of Power Sources - Volume 159, Issue 1, 13 September 2006, Pages 307–311