کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1293236 | 1498032 | 2012 | 6 صفحه PDF | دانلود رایگان |

A new method has been developed to estimate the charge capacity of LiFePO4. This method does not rely on assembly of active material, carbon and polymer binder composite electrodes, and can be used on nanoparticles with or without carbon coating. Charge capacity is derived from LiFePO4 oxidation by a solution redox mediator, 10-methylphenothiazine, in a bulk electrolysis system. The mediator serves the role of connecting the working electrode with the LiFePO4 particles suspended in the electrolyte. XRD and IR spectroscopy identified the oxidized species as heterosite-FePO4, as in standard coin cell tests. Analyses with 6.8% relative standard deviation were routinely obtained.
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► Charge capacity of LiFePO4 without test batteries.
► Charge capacity from electrolysis with solution redox mediator.
► Charge capacity from carbon and carbon free particles.
► Charge capacity independent of electrode structure.
► Average relative standard deviation for the technique 6.8%.
Journal: Journal of Power Sources - Volume 200, 15 February 2012, Pages 92–97