|کد مقاله||کد نشریه||سال انتشار||مقاله انگلیسی||ترجمه فارسی||نسخه تمام متن|
|1293319||1498252||2016||6 صفحه PDF||سفارش دهید||دانلود رایگان|
• LiVPO4F/N–C has been firstly prepared using EDA as the carbon and nitrogen source.
• The N–C coating can enhance the electronic conductivity and Li-ion diffusion.
• LiVPO4F/N–C exhibits superior electrochemical performance.
In this study, nitrogen-doped carbon is coated on LiVPO4F electrode for the first time via a simple chemical refluxing process, using ethylenediamine (EDA) as the carbon and nitrogen source. The structure, morphology and microstructure of the as-prepared electrode are characterized by XRD, XPS, Raman spectra, SEM and TEM. The uniform coating of nitrogen-doped carbon improves the electronic conductivity of LiVPO4F. As cathode material for lithium-ion batteries, the nitrogen-doped carbon coated LiVPO4F composite exhibits superior rate capability and excellent cycle performance over the carbon coated LiVPO4F. The electrode delivers an initial discharge capacity of 109.6 mAh g− 1 at high rate of 10 C and 103.1 mAh g− 1 of capacity is retained after 100 cycles. Thus, this novel modification method of nitrogen-doped carbon coating is highly effective and could be widely used to optimize the electronic conductivity of other electrode materials for lithium-ion batteries.
Figure optionsDownload as PowerPoint slide
Journal: Solid State Ionics - Volume 291, August 2016, Pages 20–25