کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1293512 1498264 2015 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ionic liquid impregnated lithium ion conductive solid electrolytes based on poly(acetyl ethylene glycol methacrylate–co-methyl acrylate)
ترجمه فارسی عنوان
الکترولیت های هدایت الکتریکی با یون لیتیوم اشباع شده یونیک بر پایه پلی اتیلن گلیکول متاکریلاتیا کو متیل اکریلات
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
چکیده انگلیسی


• Poly(AEGMA–co-MAc) copolymer was synthesized for Li ion conducting solid electrolyte.
• Tg of the copolymer is still much lower than room temperature.
• The maximum ion conductivity was 1.1 × 10− 4 S cm− 1 at 15 wt% MAc and 15 wt% of LiTFSI concentration.
• Additional introduction of TRIL further enhanced conductivity up to 1.2 × 10− 3 S cm− 1.

Poly(ethylene glycol)methacrylate (PEGMA) was modified with acetyl chloride to afford acetyl-poly(ethylene glycol)methacrylate (AEGMA) containing PEG and carbonyl groups at the pendant position. AEGMA was further reacted with methyl acrylate (MAc) to synthesize poly(AEGMA–co-MAc) copolymer containing additional carbonyl groups. When lithium salts such as lithium perchlorate (LiCLO4) and lithium bis(trifluoromethanesulfony)imides (LITFSI) were introduced into the poly(AEGMA–co-MAc) membrane, the ionic conductivity increased with increasing lithium salt concentration up to 15 wt%, followed by a decrease because when the lithium ion concentration was above its saturation level, the excess lithium salts aggregated together exerting a negative effect on ion transport. The maximum ionic conductivity of the copolymer system containing lithium salt was 1.1 × 10− 4 S cm− 1 at 15 wt% MAc and 15 wt% of LiTFSI concentration. When room temperature ionic liquid (RTIL), PYR14-TFSI in addition to LiTFSI salt was introduced to the poly(AEGMA–co-MAc)–LiTFSI, the ionic conductivity increased monotonically with increasing salt/RTIL concentration. The maximum ionic conductivity of 1.2 × 10− 3 S cm− 1 was obtained at 70 wt% 0.5 M LiTFSI/PYR14-TFSI concentration.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 279, 15 October 2015, Pages 18–24
نویسندگان
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