کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1293832 | 973574 | 2010 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Imidazolium ionic liquids containing LiBOB electrolyte for lithium battery Imidazolium ionic liquids containing LiBOB electrolyte for lithium battery](/preview/png/1293832.png)
Bis(oxlate)borate anion (BOB−) has high reduction potential for 1-ethyl-3-methyl-imdazolium tetrafluoroborate (EMIBF4) and forms solid electrolyte interface (SEI) on lithium (Li) metal surface. The addition of BOB− may make possible the use of EMIBF4 for Li metal battery. The electrochemical properties of ionic liquids containing EMIBF4 were analyzed. We investigated the stability of LiBOB/EMIBF4 and LiBF4/EMIBF4 electrolyte for Li metal and the performance of Li/MnO2 batteries with the electrolytes by 1H NMR, ac impedance spectra and the electrochemical method. From the 1H NMR spectra, LiBOB/EMIBF4 was stable for Li metal and LiBF4/EMIBF4 was reduced on the surface of Li metal. The discharge capacity of MnO2 cathode with LiBOB/EMIBF4 was 235 mAh g−1. Li metal plating and stripping and Li–Al alloying reaction were reversible in LiBOB/EMIBF4. Charge–discharge reaction of Li–Al alloy in LiBOB/EMIBF4 had a high coulomb efficiency. The coulomb efficiency at 1st cycle was 86% and the efficiency at 5th cycle was up to 94%.
Journal: Journal of Power Sources - Volume 195, Issue 5, 1 March 2010, Pages 1495–1499