کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1294100 | 973594 | 2009 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Novel Pd–Pb/C bimetallic catalysts for direct formic acid fuel cells
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
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چکیده انگلیسی
Novel carbon supported bimetallic palladium–lead (Pd–Pb/C) anode catalysts have been prepared for use in direct formic acid fuel cells (DFAFC). Comparative studies, with a Pd/C catalyst, of performances, deactivation, and reactivation were performed in a multi-anode DFAFC. These Pd–Pb/C catalysts were found to be more resistant to deactivation in the DFAFC than Pd/C and to consistently show better long-term performances. With high purity formic acid, a Pd–Pb(4:1)/C catalyst also provided superior initial performance. Initial performances are more sensitive to acetic acid in the formic acid than for Pd/C. Both the Pd–Pb/C and Pd/C catalysts can be repeatedly reactivated by applying a −0.3 V cell potential for 5 s.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 192, Issue 2, 15 July 2009, Pages 279–284
Journal: Journal of Power Sources - Volume 192, Issue 2, 15 July 2009, Pages 279–284
نویسندگان
Xingwen Yu, Peter G. Pickup,