کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1295273 | 1498259 | 2016 | 8 صفحه PDF | دانلود رایگان |
• Effect of Li+ concentration on microstructure evolution is investigated.
• Li+ concentration affects Li ionic conductivity via changing Li+ distribution.
• Optimum Li+ concentration inferred from the structure agrees with tested value.
The Li+ concentration in nominal Li7Al0.25La3Zr2O12 (LALZO) solid electrolyte are believed to pose significant effect on its electrical conductivity. The affecting mechanism of Li+ concentration on microstructure evolution and its relationship with Li ionic conductivity is investigated. Results show that Li+ occupancy in octahedral site (LiO6) increases with the increase of Li+ concentration and Li+ arrangement becomes a certain degree ordered in tetragonal site (LiO4) at 6.72 moles Li+ concentration. The structural evolution indicates that higher Li+ concentration in LiO6 as well as disordered Li+ arrangement in LiO4 will enhance the grain conductivity which infers the best Li+ concentration of 6.35 moles. The tested electrical property show the highest grain ionic conductivity of 1.35 × 10− 3 S cm− 1 at Li+ concentration of 6.35 moles which is in good agreement with prediction made from the structural evolution. It is concluded that Li+ concentration affects Li ionic conductivity via changing Li+ distribution in the grain.
Journal: Solid State Ionics - Volume 284, January 2016, Pages 53–60