کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1295752 | 1498415 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis study of alkaline-bearing rare earth phosphates with rhabdophane structure
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis study of alkaline-bearing rare earth phosphates with rhabdophane structure Synthesis study of alkaline-bearing rare earth phosphates with rhabdophane structure](/preview/png/1295752.png)
چکیده انگلیسی
The synthesis mechanism of CsCaNd(PO4)2 from nitrates, carbonates and oxides of the different cations was investigated with the aim of immobilizing cesium. Two transitory phases, a monazite-type one, NdPO4, and a poorly crystallized cesium phosphate, CsCaPO4, were proposed to explain the formation of CsCaNd(PO4)2. Direct synthesis from NdPO4 and CsCaPO4 was thus carried out. It allowed to underline that within a 900-1000 °C temperature range the rhabdophane structure, CsCaNd(PO4)2, was formed. However, the reaction was also found to be incomplete and this was assumed to be due to a lack of reactivity in concern with the high stability of monazite.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 176, Issues 35â36, 15 November 2005, Pages 2663-2669
Journal: Solid State Ionics - Volume 176, Issues 35â36, 15 November 2005, Pages 2663-2669
نویسندگان
L. Campayo, F. Audubert, D. Bernache-Assollant,