کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1296036 1498301 2013 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structural and electrical properties of Pb-substituted La2Mo2O9 oxide ion conductors
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Structural and electrical properties of Pb-substituted La2Mo2O9 oxide ion conductors
چکیده انگلیسی


• Pb-substituted La2Mo2O9 oxide ion conductors are prepared.
• Oxide ion conductivity of the present system is slightly higher than Bi-system.
• Conduction properties are discussed from the structure parameters.

Oxide ion conduction and phase transition phenomena have been investigated on La2 − xPbxMo2O9 − x/2 solid solutions (x ≤ 0.6). X-ray and neutron diffraction experiments as well as thermal analyses indicate that a single phase of high-temperature polymorph (β-phase) is preserved down to room temperature for the composition of x ≥ 0.06. In the solid solution range, ionic conductivity gradually decreases with Pb-substitution. Such phase transition and ionic conduction properties of La2 − xPbxMo2O9 − x/2 are quite similar to the Bi-substituted system, La2 − xBixMo2O9, although ionic conductivity at lower temperatures is slightly higher in the former system than the latter with the same-amount of substitution. Room temperature neutron diffraction experiment suggests that oxide-ion deficiency is introduced mainly into O2 site by the charge compensation with Pb-substitution, which would contribute to a little enhancement in conductivity compared with Bi-substituted samples along with the variation of nearest O2O3 bond length.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 238, 1 May 2013, Pages 36–43
نویسندگان
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