H3PO4-doped 1,2,4-triazole-polysiloxane proton conducting membrane prepared by sol–gel method

The development of anhydrous proton exchange membrane is critical for the polymer electrolyte membrane fuel cell (PEMFC) operating at intermediate temperature (100–200 °C). In the present work, H3PO4-doped 1,2,4-triazole-polysiloxane proton conducting membrane is successfully prepared by sol–gel reaction. The molecular structure of the PGA-xH3PO4 is confirmed via Fourier-transform infrared spectroscopy (FTIR). Thermogravimetry (TG) analysis shows that the samples were thermally stable up to approximately 250 °C. The fracture surface morphology of the materials is characterized by scanning electron microscopy (SEM). The temperature dependence of proton conductivity of all the membranes exhibits an Arrhenius behavior. The proton conductivities of these membranes increase with dopant concentration and the temperature. In an anhydrous state, the proton conductivity of PGA-1H3PO4, PGA-2H3PO4 and PGA-3H3PO4 is 1.48 × 10− 3, 1.07 × 10− 2,1.43 × 10− 2 S cm− 1 at 200 °C, respectively. According to FTIR results, the added H3PO4 is presumed to break up the hydrogen-bonding network of pure PGA, facilitating ring-reorientation and thus Grotthus mechanism proton transport. In PGA-2H3PO4, the extra H3PO4 may act as a bridge providing effective proton conduction. Therefore the proton conductivity of PGA-2H3PO4 is greatly improved compared with PGA-1H3PO4.

► H3PO4-doped 1,2,4-triazole-polysiloxane proton conducting membrane was produced by sol–gel method.
► These membranes are thermally stabled up to approximately 250 °C according to the TG analysis.
► In an anhydrous state, the proton conductivity of these proton conducting membranes can get approximately 10− 3 to 10− 2 S cm− 1 at 200 °C.
► The added H3PO4 in the samples is presumed to break up the hydrogen-bonding network, facilitating ring-reorientation and thus Grotthus mechanism proton transport.