کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1296250 | 1498261 | 2015 | 6 صفحه PDF | دانلود رایگان |
• K2NiF4-type perovskite oxides LaSrIn1 − xBxO4 + δ (B = Zr, Ti)
• NPD analysis was used in order to identify its capability of incorporating interstitial oxygen atoms.
• Interstitial oxygen atoms were identified by difference Fourier maps.
• The conductivity of these oxides was determined by ac impedance spectroscopy
• These layered perovskites were evaluated as potential ion conductors
K2NiF4-type perovskite oxides LaSrIn1 − xBxO4 + δ (B = Zr, Ti) were synthesized and characterized in order to identify its capability of incorporating interstitial oxygen atoms (δ) and their effect on the crystal structure and oxide-ion conduction. The synthesis has been performed by a citrate-nitrate soft-chemistry technique followed by annealings in air at moderate temperatures (1000 °C). The samples have been characterized at room temperature from x-ray diffraction (XRD) and the structure has been analyzed from neutron powder diffraction (NPD) data in the Pbca space group. Interstitial oxygen atoms were identified by difference Fourier maps in the NaCl layer of the K2NiF4 structure; subsequent Rietveld refinements yield excess oxygen values, δ = 0.048(4) and 0.079(5) for B = Zr with x = 0.1 and 0.2, respectively, and δ = 0.049(5) for B = Ti, x = 0.1. The performance of each oxide as a potential oxide ion conductor was evaluated by ac impedance spectroscopy using Pt as electrodes and compared with the parent compound LaSrInO4. The lowest activation energy and better ion conductivity were observed for LaSrIn0.8Zr0.2O4 + 0.08, which is consistent with the highest amount of interstitial oxygen found from NPD data.
Journal: Solid State Ionics - Volume 282, 1 December 2015, Pages 82–87