کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1297299 | 973841 | 2011 | 5 صفحه PDF | دانلود رایگان |

Solid electrolyte materials Li1.3Al0.3Ti1.7(PO4)3 (NASICON, R-3c) were synthesized via novel acetate routes A (simple precipitate), A1 (spray-dried precipitate) and B (sol–gel synthesis) and their properties are compared. Spray-dried spherical granules show characteristic features as a result of their particular microstructure. Temperature dependent DC measurements provide an informative basis to discuss two different grain boundary ionic conduction mechanisms in these spray-dried granules.
► LATP materials were synthesized via novel acetate routes.
► Particle morphology can be adjusted via synthesis conditions and processing.
► Spray-drying offers an interesting way to increase total ionic conductivity σtot.
► Two grain boundary ionic conduction mechanisms in spherical granules are discussed.
Journal: Solid State Ionics - Volume 201, Issue 1, 19 October 2011, Pages 49–53