کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1297490 | 1498403 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Lithium superionic conductors Li3InBr6 and LiInBr4 studied by 7Li, 115In NMR
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Li3InBr6 undergoes a phase transition to a superionic phase at 314 K associated with a steep increase of the conductivity (σ = 4 × 10− 3 Scm− 1 at 330 K). This superionic phase is isomorphous with Li3InCl6 in which a positional disorder at the In3+ site is introduced. A pseudo cubic-close-packing of the bromide ions is formed in this phase. On the other hand, a new superionic phase of LiInBr4 was found above ca 315 K and its structure was confirmed to be a defect spinel. The dynamic properties of the cations in these two superionic phases were investigated by 7Li and 115In NMR spectroscopy.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 177, Issues 19–25, 15 October 2006, Pages 1691–1695
Journal: Solid State Ionics - Volume 177, Issues 19–25, 15 October 2006, Pages 1691–1695
نویسندگان
Koji Yamada, Keiji Kumano, Tsutomu Okuda,