کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1297663 | 1498405 | 2006 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Effect of silane-functionalized mesoporous silica SBA-15 on performance of PEO-based composite polymer electrolytes Effect of silane-functionalized mesoporous silica SBA-15 on performance of PEO-based composite polymer electrolytes](/preview/png/1297663.png)
Silane-functionalized mesoporous silica SBA-15 particles with ultra-high specific surface area and large pore size were used as fillers in PEO-based solid electrolytes. FT-IR results confirmed the silane functionalization of SBA-15. Ionic conductivity and lithium ion transference number of the composite polymer electrolytes were found to simultaneously reach a high value of 5 wt.% silane-functionalized SBA-15 introduced in the matrix. It may be due to the combination effects of the unique structure of SBA-15 (i.e., ultra-high specific surface area and large pore size), the particularly functionalized surface of SBA-15 to promote fast ion transfer, and the good dispersion and compatibility of silane-functionalized SBA-15 in the composite polymer electrolytes. The results suggest an alternative way to improve the performance of solid polymer electrolytes.
Journal: Solid State Ionics - Volume 177, Issues 15–16, 15 June 2006, Pages 1287–1291