کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1297908 1498366 2009 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structure, defect chemistry, and proton conductivity in nominally Sr-doped Ba3La(PO4)3
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Structure, defect chemistry, and proton conductivity in nominally Sr-doped Ba3La(PO4)3
چکیده انگلیسی

The AC conductivity of eulytite-structured Ba3La(PO4)3 with 2 mol% Sr substituted for La has been investigated in the range 300–1300 °C at different oxygen and water vapor (H2O or D2O) partial pressures. The overall sample impedance has contributions from bulk (grain interior) and grain boundaries. It is concluded from the H/D isotope effect that the bulk conductivity is mainly protonic. The defect chemistry leading to a content of protons is discussed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 180, Issues 4–5, 27 April 2009, Pages 338–342
نویسندگان
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