کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1298487 1498413 2005 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Impedance spectroscopy studies of KHSO4 above room temperature
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Impedance spectroscopy studies of KHSO4 above room temperature
چکیده انگلیسی

The dielectric permittivity of polycrystalline KHSO4 was measured from 5 Hz to 13 MHz over the temperature range 51–187 °C. The corrected imaginary part of permittivity, ε″, and its real part ε′ vs. frequency clearly show a new dielectric relaxation around fmax = 1.5 * 105 Hz at 51 °C, which shifts to higher frequencies (∼ 1 MHz) as the temperatures increases. If the measurements are done when increasing the temperature, fmax decreases sharply (more than two orders of magnitude) around 164 °C; however, above this transition temperature, it continues shifting to higher frequencies as the temperature increases. However, if the measurements are done when decreasing the temperature, fmax increases abruptly around 146 °C, thus showing a hysteretic behaviour. We suggest that the observed dielectric relaxation could be produced by proton jumps and SO4− reorientation, causing distortion and changing the local lattice polarizability to induce dipoles like HSO4−.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 176, Issues 39–40, December 2005, Pages 2913–2916
نویسندگان
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