کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1298571 1498359 2009 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrocatalytic synthesis of ammonia from steam and nitrogen at atmospheric pressure
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Electrocatalytic synthesis of ammonia from steam and nitrogen at atmospheric pressure
چکیده انگلیسی

The electrocatalytic synthesis of ammonia from steam and nitrogen was studied in oxygen ion (O2−) and proton (H+) conducting solid electrolyte cells at 450–700 °C and at atmospheric total pressure. A Ru-based industrial catalyst was used as the working electrode. In the H+ cell, steam was electrolyzed at the anode to produce protons and oxygen. Protons, transported to the cathode, reacted with nitrogen to produce ammonia. In the O2− cell, H2O and N2 were fed in together at the cathode. Steam was electrolyzed and the produced hydrogen reacted with nitrogen. Ammonia formation was observed at temperatures between 500 and 700 °C. The conversions with respect to nitrogen or steam were low, primarily because of the poor conductivity of the working electrode. Both cells, however, exhibit promising features that make this alternative approach of ΝΗ3 synthesis worthy of further investigation.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 180, Issues 23–25, 5 October 2009, Pages 1332–1336
نویسندگان
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