کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1298977 1498409 2006 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ionic conductivity of polymer electrolyte membranes based on polyphosphazene with oligo(propylene oxide) side chains
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Ionic conductivity of polymer electrolyte membranes based on polyphosphazene with oligo(propylene oxide) side chains
چکیده انگلیسی

A polyphosphazene [NP(NHR)2]n with oligo[propylene oxide] side chains − R = –[CH(CH3)–CH2O]m–CH3 (m = 6 – 10) was synthesized by living cationic polymerisation and polymer-analogue substitution of chlorine from the intermediate precursor [NPCl2]n using the corresponding primary amine RNH2. The polymer had an average molecular weight of 3.3 × 105 D. Polymer electrolytes with different concentrations of dissolved lithium triflate (LiCF3SO3) were prepared. Mechanically stable polymer electrolyte membranes were formed using UV radiation induced crosslinking of the polymer salt mixture in the presence of benzophenone as photoinitiator. The glass transition temperature of the parent polymer was found to be − 75 °C before cross linking. It increases after crosslinking and with increasing amounts of salt to a maximum of − 55 °C for 20 wt.% LiCF3SO3. The ionic conductivity was determined by impedance spectroscopy in the temperature range 0–80 °C. The highest conductivity was found for a salt concentration of 20 wt.% LiCF3SO3: 6.5 × 10− 6 S·cm− 1 at 20 °C and 2.8 × 10− 4 S cm− 1 at 80 °C. The temperature dependence of the conductivities was well described by the MIGRATION concept.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 177, Issues 7–8, 15 March 2006, Pages 703–707
نویسندگان
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