کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1302703 974708 2011 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Two new self-penetrating metal-organic frameworks based on a flexible cyclohexanetetracarboxylate ligand
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Two new self-penetrating metal-organic frameworks based on a flexible cyclohexanetetracarboxylate ligand
چکیده انگلیسی

Two new metal-organic frameworks, [M2(CTA)(bipy)1.5(H2O)2]n·3n(H2O) (M = Cd for 1 and Mn for 2, H4CTA = cyclohexane-1,2,4,5-tetracarboxylic acid, bipy = 4,4′-bipyridine) have been successfully synthesized and characterized. Complexes 1 and 2 are isostructural, which display unusual three-dimensional (3D) self-penetrating coordination frameworks with 3-nodal (3,5,5)-connectivity and the Schläfli symbol of (4,6,8)(42,67,8)(43,63,83,9). Moreover, in solid state, complex 1 exhibits blue emission at ambient temperature. Magnetic measurement shows that there exist weak antiferromagnetic interactions in 2.

Graphical AbstractTwo new isostructural 3D self-penetrating metal-organic frameworks [M2(CTA)(bipy)1.5(H2O)2]n·3n(H2O) (M = Cd for 1 and Mn for 2) have been successfully synthesized and characterized. They represent the first example that using conformation flexible cyclohexane-carboxylic acid as linking ligand to construct self-penetration framework.Figure optionsDownload as PowerPoint slideResearch Highlights
► Two new isostructural 3D self-penetrating metal-organic frameworks.
► The first cyclohexane-carboxylic self-penetration framework.
► In solid state, complex 1 exhibits blue emission, and 2 shows antiferromagnetic.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 14, Issue 6, June 2011, Pages 822–825
نویسندگان
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