کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1304167 974803 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influence of meridional N3-ligands on supramolecular assembling and redox behavior of carboxylatocopper(II) complexes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Influence of meridional N3-ligands on supramolecular assembling and redox behavior of carboxylatocopper(II) complexes
چکیده انگلیسی

Mononuclear phenylglyoxylato- and 4-R-benzoatocopper(II) complexes with two different 1,3-bis(2-arylimino)isoindoline ligands (aryl = pyridyl, or benzimidazolyl) have been synthesized and characterized. Coordination mode of the carboxylate ligands is very similar (monodentate) in each case, while redox behavior of the copper center is dependent on the aryl- and 4-R-substituents. The supramolecular assembly in the solid state via hydrogen bonds and π-stacking between the ligands can be influenced by the aryl-group and carboxylate ligand.

H-bonded/p-stacked supramolecular assembling and redox properties are influenced in mononuclear carboxylatocopper(II) complexes with 1,3-bis(2-arylimino)isoindoline ligands.Figure optionsDownload as PowerPoint slideHighlights
► Carboxylatocopper(II) complexes with isoindoline-based ligands synthesized.
► Redox properties of the Cu center can be controlled.
► Rich secondary interactions induce supramolecular assembling of the complexes.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 14, Issue 11, November 2011, Pages 1767–1772
نویسندگان
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