کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1334284 | 1500235 | 2016 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis, characterization and structural study of a phosphonium salt containing the [Pd2Br6]2− ion and its application as a novel, efficient and renewable heterogeneous catalyst for amination of aryl halides and the Stille cross-coupling reaction Synthesis, characterization and structural study of a phosphonium salt containing the [Pd2Br6]2− ion and its application as a novel, efficient and renewable heterogeneous catalyst for amination of aryl halides and the Stille cross-coupling reaction](/preview/png/1334284.png)
In this study palladium(II) acetate reacts with a phosphonium salt, [Ph3PCH2C6H4CH2Br]Br, to give [Ph3PCH2C6H4CH2OC(O)CH3]2[Pd2Br6]. Characterization of the obtained compound was performed by elemental analysis, IR, 1H, 31P, 13C NMR and X-ray crystallography. It was found that this compound can act as an efficient catalyst for amination of aryl halides to afford primary amines and satisfactory results were obtained. It has also been successfully employed in the catalytic Stille cross-coupling reaction. The catalyst is easily recoverable and reusable without significant loss of its catalytic activity.
Herein a phosphonium salt containing [Pd2Br6]2− has been prepared, characterized and applied as recoverable catalyst for the Stille and amination reactions.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 105, 17 February 2016, Pages 18–26