کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1334892 | 979477 | 2010 | 7 صفحه PDF | دانلود رایگان |
The electrochemistry of the complex [Fe(CO)2(NO)2] and the IR and EPR spectra of the one-electron reduced [Fe(CO)2(NO)2]− and one-electron oxidised species [Fe(CO)2(NO)2]+ reveal mainly NO-centred spin density for the unpaired electron. The results are discussed in term of oxidation states. Furthermore, the parent complex was investigated for light-induced linkage isomerisation using IR spectroscopy. Thermally and optically reversible generation of a new species identified by new vibrational bands is interpreted in terms of photoinduced nitrosyl linkage isomers.
The redox chemistry of [Fe(CO)2(NO)2] using IR- and EPR-spectrochemistry and metastable photoinduced states using IR-spectroscopy have been studied in detail providing an insight into the frontier orbitals of this tetrahedral complex.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 29, Issue 12, 11 August 2010, Pages 2553–2559