کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1335642 979541 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hydrothermal synthesis and characterization of a new zinc phosphate [Zn2.5(HPO4)2(PO4)][C6H10N2] · 5H2O
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Hydrothermal synthesis and characterization of a new zinc phosphate [Zn2.5(HPO4)2(PO4)][C6H10N2] · 5H2O
چکیده انگلیسی
A novel two-dimensional zinc phosphate, [Zn2.5(HPO4)2(PO4)][C6N2H10] · 5H2O has been hydrothermally synthesized. The structure of this compound, determined by single crystal X-ray diffraction, represents the first one with a Zn/P ratio of 5/6. Solid-state 13C and 31P MAS NMR spectroscopies agree perfectly with the X-ray structure. Ab initio calculations allow the attribution of phosphorus and carbon signals to the independent crystallographic sites and to the various atoms of the organic groups.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 25, Issue 15, 3 November 2006, Pages 2953-2958
نویسندگان
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