Microwave-assisted facile and expeditive syntheses of phosphorescent cyclometallated iridium(III) complexes

The syntheses of greenish-blue light emitting [Ir(ppy)2(dppel)] (2), [Ir(ppy)2(dppp)] (3) and [Ir(ppy)2(dppe)] (4) [ppy, 2-phenylpyridine; dppel, 1,2-bis(diphenylphosphino)ethylene; dppp, 1,3-bis(diphenylphosphino)propane; dppe, 1,2-bis(diphenylphosphino)ethane] complexes were carried out using [(ppy)2Ir(μ-Cl)2Ir(ppy)2] (1) as a starting material. These complexes were characterized by elemental analyses and NMR (1H, 13C and 31P) spectral studies. A single-crystal X-ray diffraction study confirmed a distorted octahedral geometry for 3. Complexes 2–4 were found to exhibit blue-shifted emission as compared to [Ir(ppy)2(acac)] (acacH = acetylacetone) and [Ir(ppy)2pic] (pic = 2-picolinic acid) because of the presence of strongly π-accepting, Ph2P^PPh2 units. The solution quantum efficiency for 2–4 was measured and 2 showed the highest quantum efficiency. Ground state geometry optimizations for 2–4 were performed using density functional theory (DFT) with the B3LYP hybrid functional and excitation energies for low lying singlet and triplet excited states were obtained via time-dependent DFT (TDDFT) calculations. Further, complexes 1–4 were synthesized by a Microwave Irradiation technique (MW) in a reasonably shorter time. This facile and expeditive synthetic route has been extended and successfully verified for other heteroleptic complexes of Ir(III) with varying different bidentate [(N^N) (5), (O^O) (6), (N^O) (7)] and monodentate [PPh3 (8)] ancillary ligands.

The microwave mediated syntheses of a series of cyclometallated heteroleptic complexes of iridium(III) have been carried out and the time taken via this technique has been shown to be much shorter as compared to conventional routes. These synthesized complexes mostly emit light throughout the visible range. Complexes having phosphorous coordinating ancillary ligands showed blue-shifted emissions as compared to (O^O), (O^N) and (N^N) coordinating ligands.Figure optionsDownload as PowerPoint slide