کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1336280 | 979578 | 2011 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Unexpected radical substitution of the dichlorine-containing iron(II) clathrochelate with 1,4-dioxane derivatives: Novel approach to functionalization of its macrobicyclic framework
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Unexpected radical substitution of the dichlorine-containing iron(II) clathrochelate with 1,4-dioxane derivatives: Novel approach to functionalization of its macrobicyclic framework Unexpected radical substitution of the dichlorine-containing iron(II) clathrochelate with 1,4-dioxane derivatives: Novel approach to functionalization of its macrobicyclic framework](/preview/png/1336280.png)
چکیده انگلیسی
⺠The iron(II) clathrochelate undergoes a radical addition-elimination reactions. ⺠The reaction radical 1,4-dioxane derivatives yield C-alkylated macrobicycles. ⺠Radical substitution as a novel approach to functionalization of the clathrochelates. ⺠The free-radical addition-elimination reaction results in substitution. ⺠The reaction is first example of alkylation of a coordinated ligand with cyclic ether.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 30, Issue 7, 27 April 2011, Pages 1233-1237
Journal: Polyhedron - Volume 30, Issue 7, 27 April 2011, Pages 1233-1237
نویسندگان
Mikhail A. Vershinin, Aleksei B. Burdukov, Ilia V. Eltsov, Vladimir A. Reznikov, Evgenii G. Boguslavsky, Yan Z. Voloshin,