کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1336732 | 979608 | 2010 | 5 صفحه PDF | دانلود رایگان |
Straw-like nano-structure of a new mixed-ligand Zn(II) two-dimensional coordination polymer, {[Zn(μ-4,4′-bipy)(μ-3-bpdb)(H2O)2](ClO4)2·4,4′-bipy·3-bpdb·H2O}n (1) {4,4′-bipy = 4,4′-bipyridine and 3-bpdb = 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene}, was synthesized by a sonochemical method. The new nano-structure was characterised by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy and elemental analyses. Compound 1 was structurally characterised by single crystal X-ray diffraction and consists of two-dimensional polymeric units. ZnO nanoparticles were obtained by calcination of compound 1 at 500 °C under air atmosphere and were characterised by X-ray diffraction (XRD) and scanning electron microscopy (SEM).
Straw-like nano-structure of a new mixed-ligand Zn(II) two-dimensional coordination polymer {[Zn(μ-4,4′-bipy)(μ-3-bpdb)(H2O)2](ClO4)2·4,4′-bipy·3-bpdb·H2O}n (1), {4,4′-bipy = 4,4′-bipyridine and 3-bpdb = 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene} was synthesized by a sonochemical method. The new nano-structure was characterised by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy and elemental analyses.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 29, Issue 5, 30 March 2010, Pages 1520–1524