کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1336766 | 1500274 | 2013 | 11 صفحه PDF | دانلود رایگان |
The in situ generated new ligand (Z)-N′(1,3,4-thiadiazol-2-yl) acetimidate (tha) formed complexes [Ni(tha)2] (1), [Cu(tha)2] (2) and [Zn(tha)2] (3) in one pot condensation reactions between metal(II) acetate and 2-amino-1,3,4-thiadiazole. The complexes have been characterized with the aid of elemental analyses, IR, Raman, magnetic susceptibility and single crystal X-ray data. The metal complexes 1, 2 and 3 crystallize in monoclinic system with space group P21/c. In the complexes, the newly generated ligand is bonded through thiadiazole ring nitrogen and oxygen of acitimidate group, thus acting as N, O bidentate ligand producing a six membered chelate ring. Ni(II), Cu(II) and Zn(II) complexes of the type [ML2] contain extended hydrogen bonding providing supramolecular architecture. Various types of π–π interactions are responsible for the semiconducting behavior of the complexes and also stabilize their crystal structures. The geometry optimization has been performed using DFT method and geometrical parameters thus obtained for the complexes have been compared with their single crystal XRD structures. The molecular electrostatic potential (MEP) and contour maps of the ligand and the complexes are also calculated by DFT method.
Three new complexes [Ni(tha)2] (1), [Cu(tha)2] (2) and [Zn(tha)2] (3) have been prepared from in situ generated new ligand (Z)-N′(1,3,4-thiadiazol-2-yl) acetimidate (tha) in a single pot reaction between metal acetate and 2-amino-1,3,4-thiadiazole. In the complexes, the newly generated ligand is bonded through thiadiazole ring nitrogen and oxygen of acitimidate group, thus acting as N, O bidentate ligand producing a six membered chelate ring. The complexes show semiconducting properties due to the presence of various types of π–π interactions which also contribute to stabilize the crystal structures. The geometry optimization has been performed using DFT method and geometrical parameters thus obtained for the complexes have been compared with their crystal structures. The molecular electrostatic potential (MEP) and contour maps of ligand and the complexes are also calculated by DFT method.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 65, 28 November 2013, Pages 31–41