Pt/WO3 thin films prepared by photochemical metal–organic deposition (PMOD) and its evaluation as carbon monoxide sensor

Pure and 10% Pt-loaded tungsten oxide thin films have been successfully prepared by direct UV irradiation of bis(β-diketonate)dioxotungsten(VI) and Pt(II) precursor complexes spin-coated on Si(1 0 0) substrates. X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) techniques were used to analyze the crystal structure and chemical composition of the films before and after heat treatment at 500 °C. The results of XRD and AFM analysis showed that the as-photodeposited films are amorphous and have a rougher surface than thermally treated films. Post-annealing of the films in air at 500 °C transforms the oxides to a monoclinic WO3 phase. Gas sensing tests reveal that annealed 10% Pt/WO3 films exhibit a better response than unloaded WO3 films towards 20 ppm carbon monoxide at an operating temperature of 350 °C. The sensors also posses fast response and recovery characteristics.

Pt loaded tungsten oxide thin films have been successfully prepared by direct UV irradiation of amorphous films of β-diketonate complexes on Si(1 0 0) substrates. Photodeposited films were characterized by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Sensing capacities of the Pt/WO3 films towards carbon monoxide were evaluated.Figure optionsDownload as PowerPoint slideHighlights
► Pt-loaded WO3 thin films are photochemically deposited from β-diketonate precursors.
► Carbon monoxide sensing properties of the films were studied.
► 10%Pt–WO3 films can detect as low as 20 ppm of CO with good sensitivity.
► Best sensors operating temperature is 350 °C.