A new family of octanuclear Mn complexes with a rod-like topology

Three new octanuclear compounds were prepared from reactions of [Mn(O2CR)2]·2H2O (R = Et or Ph) with the diols 1,3-propanediol (pdH2) or 2-methyl-1,3-propanediol (mpdH2) in the presence of NaN3. All three compounds [Mn8(N3)4(O2CR)6(L)4(py)6] (L = pd2−, R = Et 1; L = mpd2−, R = Et 2; L = pd2−, R = Ph 3) (py = pyridine) possess a novel near-planar, rod-like topology. Dc and ac magnetic susceptibility studies in the 2–300 K range for complexes 1 and 2 revealed the presence of dominant antiferromagnetic exchange interactions, leading to diamagnetic ground spin states.

Three new octanuclear compounds [1, 2, and 3] (Fig.; color scheme: MnII purple, MnIII blue, O red, N green, C grey) which were prepared from the use of a combination of pdH2 or mpdH2 and N3- ligands in reactions with [Mn(O2CR)2]·2H2O (R = Et or Ph) are reported. All three compounds possess a novel [MnII6MnIII2(μ3-N3)2(μ-N3)2(μ3-OR)4(μ-OR)4]6+ structural core with a near-planar, rod-like topology.Figure optionsDownload as PowerPoint slide