کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1337985 | 979656 | 2012 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Mild formation of cyclic carbonates using Zn(II) complexes based on N2S2-chelating ligands Mild formation of cyclic carbonates using Zn(II) complexes based on N2S2-chelating ligands](/preview/png/1337985.png)
We have prepared a series of Zn(II) complexes (1–3) based on a versatile N2S2-chelating ligand abbreviated as btsc [btsc = bis-(thiosemicarbazonato)] derived from simple and accessible building blocks. These complexes comprise a Lewis acidic Zn(II) center useful for substrate activation, and we have investigated the potential of these compounds in the cyclo-addition reaction of carbon dioxide to various epoxides yielding cyclic carbonate structures. Initial screening studies with complexes 1–3 showed that complex 3 is most suited for this CO2 fixation reaction under particularly mild conditions (45 °C, pCO2 = 10 bar) and low catalyst loadings (1 mol%). Furthermore, upon examination of the substrate scope, complex 3 shows appreciable catalytic turnover for a range of terminal epoxides, while for the sterically more challenging epoxides almost no conversion was achieved under comparable conditions. Additional experiments indicated that higher yields of cyclic carbonates may be realized by simply increasing the (co)catalyst loading up to 3%, while maintaining mild reaction conditions. The use of a relatively non-toxic and abundant metal and an environmentally benign solvent system (MEK, methyl ethyl ketone) mark this protocol as an attractive way for organic carbonate production.
Zn-complexes based on btsc [bis-(thiosemicarbazonato)] ligands are effective catalysts for the conversion of carbon dioxide and terminal epoxides into cyclic carbonates with ample scope. The catalytic protocol is further characterized by low catalyst loadings, mild reaction conditions and the use of a green medium.Figure optionsDownload as PowerPoint slideHighlights
► The use of a (relatively) non-toxic metal complex for cyclic carbonate synthesis.
► The use of mild reaction conditions for this process.
► The use of a green and sustainable process for conversion of CO2.
Journal: Polyhedron - Volume 32, Issue 1, 20 January 2012, Pages 49–53