کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1337988 979656 2012 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electron-deficient tin(IV)tetraphenylporphyrin perchlorate: A highly efficient catalyst for chemical fixation of carbon dioxide
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Electron-deficient tin(IV)tetraphenylporphyrin perchlorate: A highly efficient catalyst for chemical fixation of carbon dioxide
چکیده انگلیسی

Electron-deficient tin(IV)tetraphenylporphyrin perchlorate, [SnIV(TPP)(ClO4)2] was used as a highly efficient catalyst for chemical fixation of carbon dioxide. The bifunctional catalytic system [Sn(TPP)(ClO4)2]/tetrabutylphosphonium bromide (TBPB) was applied for preparation of cyclic carbonates from epoxides and carbon dioxide. The effect of reaction parameters was also investigated.

Electron-deficient tin(IV)tetraphenylporphyrin perchlorate, [SnIV(TPP)(ClO4)2] was used as a highly efficient catalyst for chemical fixation of carbon dioxide. The bifunctional catalytic system [Sn(TPP)(ClO4)2]/tetrabutylphosphonium bromide (TBPB) was applied for preparation of cyclic carbonates from epoxides and carbon dioxide. The effect of reaction parameters was also investigated.Figure optionsDownload as PowerPoint slideHighlights
► Electron-deficient tin(IV)porphyrin was used as catalyst.
► Cyclic carbonates were obtained by the reaction of CO2 with epoxides.
► The reaction was carried out at atmospheric pressure.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 32, Issue 1, 20 January 2012, Pages 68–72
نویسندگان
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