کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1338073 | 1500270 | 2014 | 4 صفحه PDF | دانلود رایگان |
A bidentate phosphine ligand with two amide arms, designed to form hydrogen bonds with electron-donating moieties, was synthesized and isolated in high diastereomeric excess (95% de). The hydrogen-bonding abilities of the ligand and its diastereomer were demonstrated with two rhodium complexes containing these ligands. The structures of the rhodium compounds are reminiscent of the well-studied picket-fence porphyrin systems.
A bidentate phosphine ligand with two amide arms, designed to form hydrogen bonds with electron-donating moieties, was synthesized and isolated in high diastereomeric excess (95% de). The hydrogen-bonding abilities of the ligand and its diastereomer were demonstrated with two ligand-containing rhodium complexes. The structures of the rhodium compounds are reminiscent of the well-studied picket-fence porphyrin systems.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 69, 17 February 2014, Pages 156–159