کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1338298 | 979663 | 2007 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The reactions of 8-hydroxyquinoline with [RuHCl(CO)(PPh3)3]: A new ruthenium(II) carbonyl complex with a N-donor ligand
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The reaction of [RuHCl(CO)(PPh3)3] with 8-hydroxyquinoline has been examined and a novel ruthenium(II) complex - [RuCl(CO)(PPh3)2(C9H6NO)] - has been obtained. This compound has been studied by IR, UV-Vis (absorption and emission), 1H and 31P NMR spectroscopy, and X-ray crystallography. The molecular orbital diagram of the complex has been calculated with the density functional theory (DFT) method. The spin-allowed singlet-singlet electronic transitions of the complex have been calculated with the time-dependent DFT method, and the UV-Vis spectrum of the compound has been discussed on this basis.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 26, Issue 15, 20 September 2007, Pages 4201-4208
Journal: Polyhedron - Volume 26, Issue 15, 20 September 2007, Pages 4201-4208
نویسندگان
J.G. MaÅecki, R. Kruszynski, Z. Mazurak,