کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1338658 | 979674 | 2010 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and characterization of ruthenium p-cymene complexes bearing bidentate P–N and E–N ligands (E = S, Se) based on 2-aminopyridine Synthesis and characterization of ruthenium p-cymene complexes bearing bidentate P–N and E–N ligands (E = S, Se) based on 2-aminopyridine](/preview/png/1338658.png)
The syntheses and characterization of a series of cationic of Ru(II) halfsandwich complexes of the types [Ru(η6-p-cymene)(κ2(P,N)-PN)Cl]+ (PN = N-diphenylphosphino-2-aminopyridine, N-di-iso-propylphosphino-2-aminopyridine, 2-[(2-pyridyl)amino]dibenzo[d,f][1,2,3]dioxaphosphepine, N-(diisopropylphosphino)-2,6-diaminopyridine) and [Ru(η6-p-cymene)(κ2(E,N)-EN)Cl]+ (EN = N-(2-pyridinyl)amino-diphenylphosphine sulfide, N-(2-pyridinyl)amino-diisopropylphosphine sulfide, N-(2-pyridinyl)amino-diphenylphosphine selenide, N-(2-pyridinyl)amino-diisopropylphosphine selenide) is described. Some of these complexes were tested as precatalysts for the transfer hydrogenation of acetophenone to give 1-phenyl ethanol.
Several complexes of the types [Ru(η6-p-cymene)(PN)Cl]+ and [Ru(η6-p-cymene)(EN)Cl]+ containing aminophosphine ligands based on 2-aminopyridine were prepared and characterized. Some of these complexes were tested as precatalysts for the transfer hydrogenation of acetophenone to give 1-phenyl ethanol.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 29, Issue 16, 29 October 2010, Pages 3097–3102