کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1339534 | 979707 | 2010 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Equilibrium and kinetic studies of reactions of [MnN(H2O)(CN)4]2− with monodentate ligands and the molecular structure of [MnN(NCS)(CN)4]3− Equilibrium and kinetic studies of reactions of [MnN(H2O)(CN)4]2− with monodentate ligands and the molecular structure of [MnN(NCS)(CN)4]3−](/preview/png/1339534.png)
The dissolution of [(CH3)N]2Na[MnN(CN)5]·H2O in water results in the dissociation of the labile trans-CN ligand to form [MnN(H2O)(CN)4]2−(aq). The formed aqua complex reacts rapidly with a number of nucleophiles such as NCS− and N3−. Here we report the single crystal X-ray structure of the reaction products of as well as the equilibrium and kinetic behaviour of [MnN(H2O)(CN)4]2− in solution.
The dissolution of [(CH3)N]2Na[MnN(CN)5]·H2O in water results in the dissociation of the labile trans-CN ligand to form [MnN(H2O)(CN)4]2−(aq). The formed aqua complex reacts rapidly with a number of nucleophiles such as NCS− and N3−. Here, we report the single crystal X-ray structure of the reaction products of as well as the kinetic behaviour of [MnN(H2O)(CN)4]2− in solution.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 29, Issue 1, 13 January 2010, Pages 470–476