کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1339534 979707 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Equilibrium and kinetic studies of reactions of [MnN(H2O)(CN)4]2− with monodentate ligands and the molecular structure of [MnN(NCS)(CN)4]3−
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Equilibrium and kinetic studies of reactions of [MnN(H2O)(CN)4]2− with monodentate ligands and the molecular structure of [MnN(NCS)(CN)4]3−
چکیده انگلیسی

The dissolution of [(CH3)N]2Na[MnN(CN)5]·H2O in water results in the dissociation of the labile trans-CN ligand to form [MnN(H2O)(CN)4]2−(aq). The formed aqua complex reacts rapidly with a number of nucleophiles such as NCS− and N3−. Here we report the single crystal X-ray structure of the reaction products of as well as the equilibrium and kinetic behaviour of [MnN(H2O)(CN)4]2− in solution.

The dissolution of [(CH3)N]2Na[MnN(CN)5]·H2O in water results in the dissociation of the labile trans-CN ligand to form [MnN(H2O)(CN)4]2−(aq). The formed aqua complex reacts rapidly with a number of nucleophiles such as NCS− and N3−. Here, we report the single crystal X-ray structure of the reaction products of as well as the kinetic behaviour of [MnN(H2O)(CN)4]2− in solution.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 29, Issue 1, 13 January 2010, Pages 470–476
نویسندگان
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