کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1339754 979714 2007 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Bis(triphenylphosphine)4-fluorobenzaldehyde thiosemicarbazone copper(I): Forcing chelation through oxoanions
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Bis(triphenylphosphine)4-fluorobenzaldehyde thiosemicarbazone copper(I): Forcing chelation through oxoanions
چکیده انگلیسی

This paper reports the synthesis and characterization of six compounds of copper(I), stabilized in its reduced state by two triphenylphosphines, in which 4-fluorobenzaldehyde thiosemicarbazone and N-methylthiosemicarbazone act as chelating through their sulfur and imino nitrogen. The three oxoanions that have been chosen, NO3−, SO42− and CH3COO−, play an important role: their oxygens are bad competitors with the imino nitrogen of the thiosemicarbazone moiety and moreover they form strong charge assisted hydrogen bondings that stabilize the neutral form of the ligand. The overall packing is determined by intermolecular phenyl–phenyl van der Waals interactions.

Six 4-fluorobenzaldehyde thiosemicarbazone and 4-fluoro-4N-methylthiosemicarbazone bis(triphenylphosphine) copper(I) complexes with different oxoanions were synthesized and characterized, for three of them the crystal structure was determined. The structures are the first reported in the literature in which a thiosemicarbazone binds as chelate on a bis(triphenylphosphine)copper(I). The role of the oxoanions is determinant in stabilizing the Z configuration without competing as ligands.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 26, Issue 14, 31 August 2007, Pages 3774–3782
نویسندگان
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